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Synthesis, structure, and photodecarboxylation of cobalt(III) complexes with diethylenetriamine and L-ornithine [Co(Dien)(Orn)](ClO4)2 ยท 0.5H2O or DL-histidine [Co(Dien)(His)](ClO4)2
- Source :
- Russian Journal of Inorganic Chemistry. 54:686-691
- Publication Year :
- 2009
- Publisher :
- Pleiades Publishing Ltd, 2009.
-
Abstract
- Mixed cobalt(III) complexes with diethylenetriamine (Dien) and a tridentate anion of L-ornithine (Orn) [Co(Dien)(His)](ClO4)2 · 0.5 H2O or DL-histidine (His) [Co(Dien)(Orn)](ClO4)2 are synthesized. According to the X-ray diffraction studies, the secondary N atom of diethylenetriamine is trans to the donor N atom of the side chain of the amino acid. Organometallic products of photodecarboxylation of the complexes are isolated by ion exchange chromatography. The electronic absorption spectra indicate that the products contain three-membered Co-C-N rings.
- Subjects :
- chemistry.chemical_classification
Absorption spectroscopy
Stereochemistry
Materials Science (miscellaneous)
Ion chromatography
chemistry.chemical_element
Ion
Amino acid
Inorganic Chemistry
chemistry.chemical_compound
chemistry
Diethylenetriamine
Side chain
Physical and Theoretical Chemistry
Cobalt
Histidine
Subjects
Details
- ISSN :
- 15318613 and 00360236
- Volume :
- 54
- Database :
- OpenAIRE
- Journal :
- Russian Journal of Inorganic Chemistry
- Accession number :
- edsair.doi...........810a406275e85d460649ff94849b9391