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ZIF-L-Co@carbon fiber paper composite derived Co/Co3O4@C electrocatalyst for ORR in alkali/acidic media and overall seawater splitting
- Source :
- International Journal of Hydrogen Energy. 45:33028-33036
- Publication Year :
- 2020
- Publisher :
- Elsevier BV, 2020.
-
Abstract
- Green and clean energy technologies, including fuel cells, metal-air batteries, water splitting et al., are becoming more significant for our lives. Oxygen reduction reaction (ORR), hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) are key reaction processes for fuel cells, metal-air batteries and water splitting. Therefore, it is highly desirable to design a multifunctional catalyst, which owns catalytic performance under a widely applied range. Herein, we demonstrate a novel multifunctional catalyst (Co/Co3O4@C) by carbonizing a composite material constructed of zeolite imidazolate framework and carbon fiber paper (ZIF-L-Co@CP). It is a carbon-based material containing metallic Co and Co3O4 as a low-cost and effective catalyst toward the ORR and overall water splitting. For ORR, the Co/Co3O4@C catalyst shows high half-wave potential in both alkaline and acidic media, 0.823 V for 0.1 M KOH and 0.672 V for 0.1 M HClO4. More importantly, it exhibits good catalytic activities of hydrogen and oxygen evolutions to perform overall splitting in actual seawater.
- Subjects :
- Materials science
Hydrogen
Renewable Energy, Sustainability and the Environment
Carbonization
Oxygen evolution
Energy Engineering and Power Technology
chemistry.chemical_element
02 engineering and technology
010402 general chemistry
021001 nanoscience & nanotechnology
Condensed Matter Physics
Electrocatalyst
01 natural sciences
Oxygen
0104 chemical sciences
Catalysis
Fuel Technology
chemistry
Chemical engineering
Water splitting
0210 nano-technology
Zeolite
Subjects
Details
- ISSN :
- 03603199
- Volume :
- 45
- Database :
- OpenAIRE
- Journal :
- International Journal of Hydrogen Energy
- Accession number :
- edsair.doi...........80b7d3c5f02dd6593b1d42c9f251c5fa