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Catalytic reactions of samarium (II) iodide

Authors :
E. J. Corey
Gengfeng Zheng
Source :
Tetrahedron Letters. 38:2045-2048
Publication Year :
1997
Publisher :
Elsevier BV, 1997.

Abstract

A system for in situ regeneration of SmI2 from SmI3 is described which allows the annulation of ketones to γ-lactones, the deoxygenation of oxiranes to olefins and radical π-cyclization to be conducted with 10 mole % SmI2.

Details

ISSN :
00404039
Volume :
38
Database :
OpenAIRE
Journal :
Tetrahedron Letters
Accession number :
edsair.doi...........803d5026468356c9c3aa4787bbd95eb7
Full Text :
https://doi.org/10.1016/s0040-4039(97)00263-3