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The termination mechanism for radical oligomerization of methacrylonitrile

Authors :
David H. Solomon
Algirdas K. Serelis
Source :
Polymer Bulletin. 7
Publication Year :
1982
Publisher :
Springer Science and Business Media LLC, 1982.

Abstract

Decomposition of azobisisobutyronitrile in benzene containing small amounts of methacrylonitrile produces a mixture of oligomers of methacrylonitrile. Analysis by gas chromatography-mass spectrometry indicates that combination is the preponderant (>90%) termination mechanism.

Subjects

Subjects :
Polymers and Plastics
Azobisisobutyronitrile
General Chemistry
Condensed Matter Physics
Mass spectrometry
Photochemistry
Decomposition
chemistry.chemical_compound
chemistry
Mechanism (philosophy)
Methacrylonitrile
Polymer chemistry
Materials Chemistry
Benzene

Details

ISSN :
14362449 and 01700839
Volume :
7
Database :
OpenAIRE
Journal :
Polymer Bulletin
Accession number :
edsair.doi...........80286059338011e669bcb66be03068f0

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