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Enantioselective oxidation of sulphides by dioxiranes in the presence of bovine serum albumin

Authors :
Nicoletta Gaggero
Stefano Colonna
Source :
Tetrahedron Letters. 30:6233-6236
Publication Year :
1989
Publisher :
Elsevier BV, 1989.

Abstract

Oxidation of sulphides by in situ generated dioxiranes in buffered (pH 7.5) aqueous solutions, using bovine serum albumin (BSA) as a chiral auxiliary, affords the corresponding sulphoxides in up to 89% enantiomeric excess (e.e.).

Details

ISSN :
00404039
Volume :
30
Database :
OpenAIRE
Journal :
Tetrahedron Letters
Accession number :
edsair.doi...........7fe5d098a1288c3dc6e632af76882154
Full Text :
https://doi.org/10.1016/s0040-4039(01)93352-0