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Gold self-relay catalysis for accessing functionalized cyclopentenones bearing an all-carbon quaternary stereocenter

Authors :
Bo Jiang
Tian-Shu Zhang
Shu-Jiang Tu
Jing-Long Chen
Xiao-Yan Qin
Wen-Juan Hao
Fan-Tao Meng
Source :
Organic Chemistry Frontiers. 9:140-146
Publication Year :
2022
Publisher :
Royal Society of Chemistry (RSC), 2022.

Abstract

A new gold(i) self-relay catalysis consisting of a 3,3-rearrangement, Nazarov cyclization and Michael addition cascade of 1,3-enyne acetates with aurones and their derived azadienes is reported, producing functionalized cyclopentenones.

Details

ISSN :
20524129
Volume :
9
Database :
OpenAIRE
Journal :
Organic Chemistry Frontiers
Accession number :
edsair.doi...........7f7940bc1fbba30d9921147eb770fa06