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α-Diimine synthesis via titanium-mediated multicomponent diimination of alkynes with C-nitrosos
- Source :
- Chemical Science. 13:1469-1477
- Publication Year :
- 2022
- Publisher :
- Royal Society of Chemistry (RSC), 2022.
-
Abstract
- Alkyne diimination to unsymmetric α-diimines can be achieved via multicomponent reaction of Ti imidos and C-nitrosos. C-nitroso [4 + 2] cycloaddition across a diazatitanacyclohexadiene initiates cascading retrocycloadditions, liberating the α-diimine.
- Subjects :
- General Chemistry
Subjects
Details
- ISSN :
- 20416539 and 20416520
- Volume :
- 13
- Database :
- OpenAIRE
- Journal :
- Chemical Science
- Accession number :
- edsair.doi...........7f2ece9711da62f0b5faf78704976024