Ligand-Acceleration by a Chiral Modifier in the Enantioselective Hydrogenation of Methyl Acetoacetate on a Raney Nickel Catalyst: Effect of a Modifier Configuration

Authors :: Ryo-Ichi Tsukiyama
Satoshi Nakagawa
Naoya Kamata
Tadashi Okuyama
Takashi Sugimura
Takahiro Tei
Takashi Tajiri
Yasuaki Okamoto
Source :: Bulletin of the Chemical Society of Japan. 88:271-276
Publication Year :: 2015
Publisher :: The Chemical Society of Japan, 2015.
Abstract: Reaction rate and enantioselectivity of asymmetric hydrogenation of methyl acetoacetate were studied over Raney nickel catalysts modified with (R,R)-tartaric acid, malic acid, or succinic acid to r...

Subjects :: inorganic chemicals
Ligand
Asymmetric hydrogenation
Enantioselective synthesis
food and beverages
General Chemistry
Raney nickel
Catalysis
Reaction rate
chemistry.chemical_compound
chemistry
Succinic acid
Organic chemistry
Malic acid

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