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Zinc and iron complexes of a helix-directing (1R,2R)-cyclohexyl salen ligand with phenanthryl sidearms
- Source :
- Canadian Journal of Chemistry. 87:224-231
- Publication Year :
- 2009
- Publisher :
- Canadian Science Publishing, 2009.
-
Abstract
- A symmetrical salen ligand is formed by the condensation of (1R,2R)-diaminocyclohexane with 4-hydroxy-3-phenanthrenecarboxaldehyde. Crystallographic characterization of the metal complexes (ZnII, FeII, and FeIII) show 1:1 mixtures of diastereomeric M and P helical molecules. ECD spectra of the ZnII complex combined with DFT simulations strongly suggest that the M conformation is dominant in solution. This is supported by 1H and 13C NMR data, which are consistent with a single species in solution.Key words: zinc, iron, ECD, DFT, salen complexes.
Details
- ISSN :
- 14803291 and 00084042
- Volume :
- 87
- Database :
- OpenAIRE
- Journal :
- Canadian Journal of Chemistry
- Accession number :
- edsair.doi...........7ca7c4a689e54b1adf1417b2c92d0a6c