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Dual-Emissive Langmuir–Blodgett Films of a 9,9-Bis(4-ethynylphenyl)fluorene Derivative of Gold(I) and Some Europium-Substituted Polyoxometalates: Preparation, Characterization and Photoelectric Properties
- Source :
- Journal of Inorganic and Organometallic Polymers and Materials. 22:97-104
- Publication Year :
- 2011
- Publisher :
- Springer Science and Business Media LLC, 2011.
-
Abstract
- A new family of organometallic/inorganic composite Langmuir–Blodgett (LB) films consisting of the rigid-rod dinuclear gold(I) complex coordinated with 9,9-bis(4-ethynylphenyl)fluorene (denoted as Au-DPF) as the π-conjugated organometallic molecule coupled with some europium-substituted polyoxometalates (POM; POM = Na9EuW10O36, K13[Eu(SiW11O39)2] and K5[Eu(SiW11O39)(H2O)2]) as the inorganic component were prepared and characterized by π–A isotherms, UV–vis absorption and photoluminescence spectra, atomic force microscopy imaging, scanning tunneling microscopy, and surface photo-voltage spectroscopy. Luminescence spectra of the prepared hybrid LB films show that the near-white emission spectra can be obtained due to the dual-emissive nature of the mixed Au-DPF/POM blends, and POM can facilitate broad aggregate emission bands. These Au-diyne-based LB films displayed interesting electric conductivity behavior. Among them, Au-DPF/K13[Eu(SiW11O39)2] 13-layer film showed a good electrical response, with the tunneling current up to ±100 nA when the voltage was monitored between −1.3 and 1.8 V. The photovoltage response of Au-DPF/EuW22 amounts to 1.5 μV.
- Subjects :
- Materials science
Photoluminescence
Polymers and Plastics
chemistry.chemical_element
Fluorene
Langmuir–Blodgett film
law.invention
chemistry.chemical_compound
chemistry
law
Polyoxometalate
Materials Chemistry
Organic chemistry
Molecule
Physical chemistry
Scanning tunneling microscope
Europium
Spectroscopy
Subjects
Details
- ISSN :
- 15741451 and 15741443
- Volume :
- 22
- Database :
- OpenAIRE
- Journal :
- Journal of Inorganic and Organometallic Polymers and Materials
- Accession number :
- edsair.doi...........7c962e40fd4074fda26c7f56395fb040