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Direct oxidative functionalization of saturated dispiro-cyclopropanated bicyclo[3.3.1]nonanes

Authors :
Tamara S. Kuznetsova
Yuri K. Grishin
Igor P. Gloriosov
Kristian S. Andriasov
Elena B. Averina
Kseniya N. Sedenkova
Marina G. Eremenko
Source :
Mendeleev Communications. 31:294-296
Publication Year :
2021
Publisher :
Elsevier BV, 2021.

Abstract

Two dispiro[cyclopropane-1,3’-bicyclo[3.3.1]nonane-7′,1″-cyclopropanes] were treated with various oxidative systems. The conditions providing mono- or dioxidation of the CH2 groups neighbouring to spiro-annulated cyclopropane moieties to afford the corresponding mono- or diketones were found.

Details

ISSN :
09599436
Volume :
31
Database :
OpenAIRE
Journal :
Mendeleev Communications
Accession number :
edsair.doi...........7a4be32380c72ac380016db1d3622e34