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Synthesis and Thermal Decomposition Studies of Silicon (IV) Compounds with N,Nā-Bis(Salicylidene)Ethylenediimine
- Source :
- Silicon. 9:159-163
- Publication Year :
- 2015
- Publisher :
- Springer Science and Business Media LLC, 2015.
-
Abstract
- The silicon (IV) compounds possessing SiN4O2 (6), SiN2O2C2 (7, 8), SiN2O2CCl (9) and SiN4O4 (10) coordinating frameworks have been synthesized in high yield by the reaction of the O,N,N,O- donor salen-type ligand N,Nā-bis(salicylidene)ethylenediimine L with different silanes i.e. diethoxydiisocyanatosilane-(C2H5O)2Si(NCO)2 1, dichlorodiphenylsilane-Ph2SiCl2 2, dichloromethyl- phenylsilane-MePhSiCl2 3, trichlorophenylsilane-PhSiCl3 4 and silicon tetrachloride-SiCl4 5. The compounds 6ā10 have been characterized by elemental analysis, IR, 1H, 13C and 29Si NMR and mass spectrometry. The decomposition reactivity of these compounds has been studied using a Thermal Gravimetric Analyzer (TGA) at a heating rate of 10°C/minute in an inert atmosphere.
- Subjects :
- Silanes
Silicon
010405 organic chemistry
Inorganic chemistry
Thermal decomposition
chemistry.chemical_element
010402 general chemistry
Mass spectrometry
01 natural sciences
Silane
0104 chemical sciences
Electronic, Optical and Magnetic Materials
chemistry.chemical_compound
chemistry
Salen ligand
Gravimetric analysis
Reactivity (chemistry)
Nuclear chemistry
Subjects
Details
- ISSN :
- 18769918 and 1876990X
- Volume :
- 9
- Database :
- OpenAIRE
- Journal :
- Silicon
- Accession number :
- edsair.doi...........79faa33975276981241a794991e9c13a