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On the visco-elastic and dielectric behaviour of two alcohols and their binary mixture

Authors :
Mohan T. Hosamani
Narasimha H. Ayachit
D.K. Deshpande
Source :
Physics and Chemistry of Liquids. 49:639-647
Publication Year :
2011
Publisher :
Informa UK Limited, 2011.

Abstract

Inter-molecular and intra-molecular interactions in liquids determine the physical properties of the systems. These interactions are understood through the measurement of these physical properties. These become especially important in the case of alcohols in view of the specific type of interactions involved. Study of the variation of dielectric relaxation time with the viscosity of the medium is relevant in drawing certain quantitative conclusions regarding molecular motion and the inter-molecular forces in liquids, liquid mixtures, dilute solutions and multi-component polar solutes in dilute solution. In the absence of a perfect empirical or theoretical equation for the variation of dielectric relaxation time with viscosity, the experimental investigations on different systems can only give an insight. In the present study, the results of dielectric measurements carried out on pure samples of methyl alcohol and propyl alcohol in dilute solutions in different mixed solvents (benzene + paraffin) and on bi...

Details

ISSN :
10290451 and 00319104
Volume :
49
Database :
OpenAIRE
Journal :
Physics and Chemistry of Liquids
Accession number :
edsair.doi...........79a78bac643e9f060e351bc85bc9f6c7
Full Text :
https://doi.org/10.1080/00319104.2010.490947