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(Diacetoxyiodo)benzene-Mediated Oxygenation of Benzylic C(sp3)-H Bonds withN-Hydroxyamides at Room Temperature

Authors :
Yu Liu
Peng-Cheng Qian
Ming Hu
Jin-Heng Li
Xu-Heng Yang
Ren-Jie Song
Jiannan Xiang
Source :
European Journal of Organic Chemistry. 2015:1680-1684
Publication Year :
2015
Publisher :
Wiley, 2015.

Abstract

A new, metal-free method for the formation of C(sp3)–O bonds was established by PhI(OAc)2-mediated oxygenation of benzylic C(sp3)–H bonds with N-hydroxyamides at room temperature, in which the C(sp3)–H oxidation is activated by a polyflurophenylamide group.

Details

ISSN :
1434193X
Volume :
2015
Database :
OpenAIRE
Journal :
European Journal of Organic Chemistry
Accession number :
edsair.doi...........7976f2e828cc12da26783bef9b8ebfc4
Full Text :
https://doi.org/10.1002/ejoc.201403616