Back to Search Start Over

A Novel Method for the Chlorolactonization of Alkenoic Acids Using Diphenyl Sulfoxide/Oxalyl Chloride

Authors :
Liyuan Lan
Baoguo Sun
Hongyu Tian
Yongguo Liu
Rui Ding
Li Shuhui
Shaoxiang Yang
Source :
Synthesis. 50:2555-2566
Publication Year :
2018
Publisher :
Georg Thieme Verlag KG, 2018.

Abstract

A facile chlorolactonization of alkenoic acids by treatment with diphenyl sulfoxide/oxalyl chloride has been developed. The reaction can generate various chlorolactones in moderate to good yields, wherein the chlorodiphenylsufonium salt derived from diphenyl sulfoxide/oxalyl chloride serves as the source of Cl+.

Details

ISSN :
1437210X and 00397881
Volume :
50
Database :
OpenAIRE
Journal :
Synthesis
Accession number :
edsair.doi...........77dbf0ed89645147aa3a30c1025b7cf5