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Diols obtained via chemo and regioselective ring opening of epoxy alcohols: a straightforward synthesis of 2S,3S-Octandiol
- Source :
- Tetrahedron. 48:1531-1538
- Publication Year :
- 1992
- Publisher :
- Elsevier BV, 1992.
-
Abstract
- epoxy alcohols are regio and chemoselectively opened to the corresponding iodohydrins and then reduced in situ to diols; the application of the described procedure leads to a short asymmetric of a well known pheromone. Also homoallylic (E and Z) epoxy alcohols and its benzylated derivatives shows high preference for regioselective opening affording the corresponding 1,3 diol.
- Subjects :
- inorganic chemicals
organic chemicals
Organic Chemistry
Cyclohexane-1,2-diol
Diol
Enantioselective synthesis
Regioselectivity
Epoxide
Epoxy
Biochemistry
chemistry.chemical_compound
chemistry
visual_art
Drug Discovery
polycyclic compounds
visual_art.visual_art_medium
Organic chemistry
heterocyclic compounds
Chemoselectivity
Aliphatic compound
Subjects
Details
- ISSN :
- 00404020
- Volume :
- 48
- Database :
- OpenAIRE
- Journal :
- Tetrahedron
- Accession number :
- edsair.doi...........7766dc44ad03972080049216e4dc2412