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Mono-C-alkylation of β-dicarbonyl compounds using tetraethylammonium fluoride

Authors :
James H. Clark
Jack M. Miller
Source :
J. Chem. Soc., Chem. Commun.. :64-65
Publication Year :
1977
Publisher :
Royal Society of Chemistry (RSC), 1977.

Abstract

The hydrogen-bonded solvates formed between tetraethylammonium fluoride and a number of β-dicarbonyl compounds react at about room temperature with alkyl iodides to provide high yields of the mono-C-alkylated β-dicarbonyl products with no apparent contamination due to the formation of O-alkyl, dialkyl, or polymerisation products.

Details

ISSN :
00224936
Database :
OpenAIRE
Journal :
J. Chem. Soc., Chem. Commun.
Accession number :
edsair.doi...........76ee23541bb0a4f8f7ce7f1b8ff9f143
Full Text :
https://doi.org/10.1039/c39770000064