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KOtBu-mediated aromatic O-glycosylation of 1,2-anhydrosugar and aryl boronic acid
- Source :
- Tetrahedron Letters. 57:1372-1374
- Publication Year :
- 2016
- Publisher :
- Elsevier BV, 2016.
-
Abstract
- A new approach for the synthesis of phenolic glycosides via aromatic O-glycosylation of 1,2-anhydrosugar and aryl boronic acids was disclosed. This method is characterized by the use of aryl boronic acid as the aryl source and produces phenolic glycosides in a stereoselective manner. This reaction provides an alternative approach to the synthesis of phenolic glycosides. It also represents a new application of aryl boronic acids as versatile reagents in organic synthesis.
- Subjects :
- inorganic chemicals
chemistry.chemical_classification
Glycosylation
010405 organic chemistry
Aryl
Organic Chemistry
Glycoside
010402 general chemistry
01 natural sciences
Biochemistry
0104 chemical sciences
chemistry.chemical_compound
chemistry
Reagent
Drug Discovery
Organic chemistry
Stereoselectivity
Organic synthesis
Boronic acid
Subjects
Details
- ISSN :
- 00404039
- Volume :
- 57
- Database :
- OpenAIRE
- Journal :
- Tetrahedron Letters
- Accession number :
- edsair.doi...........764db56702861487a5e7cbf412b34b55