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Mechanochemical sulfonation of aromatic compounds using NaHSO4·H2O/P2O5

Authors :
Zhi-Xin Guo
Yujun Qin
Shuai Qin
Lu-Lu Zuo
Pu Zhang
Source :
Journal of Chemical Research. 45:942-949
Publication Year :
2021
Publisher :
SAGE Publications, 2021.

Abstract

A series of aromatic sulfonic acids is synthesized by subjecting arenes and NaHSO4·H2O to high-speed ball milling in the presence of P2O5. It is suggested the aromatic sulfonation occurs via in situ generated H2SO4 to give aromatic sulfonic acids. In some cases, formation of diaryl sulfones was observed.

Details

ISSN :
20476507 and 17475198
Volume :
45
Database :
OpenAIRE
Journal :
Journal of Chemical Research
Accession number :
edsair.doi...........7613fdd438322fc5a2576328e494fef2
Full Text :
https://doi.org/10.1177/17475198211032571