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ChemInform Abstract: Quaternary Pnictides with Complex, Noncentrosymmetric Structures. Synthesis and Structural Characterization of the New Zintl Phases Na11Ca2Al3Sb8, Na4CaGaSb3, and Na15Ca3In5Sb12

Authors :
Svilen Bobev
Yi Wang
Stanislav S. Stoyko
Source :
ChemInform. 46
Publication Year :
2015
Publisher :
Wiley, 2015.

Abstract

Single crystals of the new title Zintl phases are prepared by solid state reactions from mixtures of the elements in the molar ratio of Na:Ca:M:Sb = 3:3:1:4 (M: Al, Ga, In) in sealed Nb containers (1173 K, 24 h).

Details

ISSN :
09317597
Volume :
46
Database :
OpenAIRE
Journal :
ChemInform
Accession number :
edsair.doi...........75f775e8b8e8d6f9fca95b2375d5b5af
Full Text :
https://doi.org/10.1002/chin.201517016