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A fluxional tetraplatinum cluster: solution and solid state structure of the cation [Pt4(µ-H)(µ-CO)2(µ-Ph2PCH2PPh2)3(Ph2PCH2PPh2)]+
- Source :
- J. Chem. Soc., Chem. Commun.. :149-150
- Publication Year :
- 1988
- Publisher :
- Royal Society of Chemistry (RSC), 1988.
-
Abstract
- The 58-electron cationic cluster complex [Pt4(µ-H)(µ-CO)2(µ-dppm)3(dppm-P)]+, dppm = Ph2PCH2PPh2, has been characterized in solution by n.m.r. spectroscopy and in the solid by X-ray analysis of the PF6– salt; the cation displays novel fluxionality with rapid rotation of a µ-H below and a µ-Pt(CO)2(dppm-P) unit above a Pt3(µ-dppm)3+ triangle.
Details
- ISSN :
- 00224936
- Database :
- OpenAIRE
- Journal :
- J. Chem. Soc., Chem. Commun.
- Accession number :
- edsair.doi...........7584808955a542979bd803543ed7f730