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Sol-gel MgO coating on glass microspheres for inhibiting excessive interfacial reaction in Al-Mg matrix syntactic foam
- Source :
- Journal of Alloys and Compounds. 798:59-66
- Publication Year :
- 2019
- Publisher :
- Elsevier BV, 2019.
-
Abstract
- Glass microspheres are considered to be suitable fillers in syntactic foams due to their high specific strength, however, it's evidently easy to react with Al-Mg alloy or Mg alloy. A surface protection coating MgO were successfully prepared on microspheres using sol-gel method. The crystallization process and coating effect of MgO with different molar ratio acetic acid complexant in sol compositions were studied. The dried gels were dehydrated and polycondensed to form magnesium acetate and finally turned to be stable MgO after annealing at 400 °C. The MgO coatings, with small particles after annealing, successfully modified the surface of microspheres when the sol composition (molar) magnesium acetate hydrate/acetic acid/dry ethanol was 1:6:29. The MgO coating has inhibited the excessive interfacial reaction between the glass microspheres and the Al-Mg alloy matrix in syntactic foam which the reasons have been discussed.
- Subjects :
- Materials science
Syntactic foam
Alloy
02 engineering and technology
engineering.material
010402 general chemistry
01 natural sciences
law.invention
Acetic acid
chemistry.chemical_compound
Coating
law
Materials Chemistry
Crystallization
Sol-gel
Mechanical Engineering
Metals and Alloys
Magnesium acetate
021001 nanoscience & nanotechnology
0104 chemical sciences
Glass microsphere
chemistry
Chemical engineering
Mechanics of Materials
engineering
0210 nano-technology
Subjects
Details
- ISSN :
- 09258388
- Volume :
- 798
- Database :
- OpenAIRE
- Journal :
- Journal of Alloys and Compounds
- Accession number :
- edsair.doi...........755b2b03eade9e6de0edd35556e89bab