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Ni/SDC Nanoparticles Modified La[sub 0.75]Sr[sub 0.25]Cr[sub 0.5]Fe[sub 0.5]O[sub 3−δ] as Anodes for Solid Oxide Fuel Cells

Authors :
Xingbao Zhu
Bo Wei
Xiqiang Huang
Zhe Lü
Kongfa Chen
Wenhui Su
Mingliang Liu
Source :
Electrochemical and Solid-State Letters. 12:B161
Publication Year :
2009
Publisher :
The Electrochemical Society, 2009.

Abstract

Fe-doped (La,Sr)CrO 3―δ (LSCrFe) oxide was modified as the anode of solid oxide fuel cells. Through vacuum-assisted impregnation processes, nanosized Sm-doped CeO 2 (SDC) and Ni particles were introduced into an anode backbone. With Ni and SDC coimpregnated LSCrFe anodes, the maximum power densities at 900°C reached 765 and 271 mW cm ―2 with H 2 and CH 4 as fuels, respectively, which were much higher than that with a nonmodified LSCrFe anode. Our results indicated that nanosized Ni particles played a primary role in performance enhancement. No carbon deposition was detected for all tested LSCrFe-based anodes.

Details

ISSN :
10990062
Volume :
12
Database :
OpenAIRE
Journal :
Electrochemical and Solid-State Letters
Accession number :
edsair.doi...........74a98e82c02cdbedad424a69f766e9aa