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Parameter optimization of copper nanoparticle synthesis by electrodeposition process using RSM and CS

Authors :
P. Selvakumar
B. Madhankumar
Thangamuthu Mohanraj
A. Tamilvanan
K. Balamurugan
Source :
Materials Today: Proceedings. 45:751-756
Publication Year :
2021
Publisher :
Elsevier BV, 2021.

Abstract

Now-a-days, more concentration attention has been given for synthesizing of copper (Cu) nanoparticles due to its excellent physical and chemical properties. Different approaches are available to synthesize the Cu nanoparticles. Electrodeposition is an easier and simple approach to synthesize the Cu nanoparticles with high purity. The properties of Cu nanoparticles depend on their synthesis approach and electrolysis process parameters. In this work, response surface methodology (RSM), cuckoo search (CS) algorithm was used to optimize the electrodeposition process parameters like concentration of CuSO4 (4–6 g l−1), electrode potential difference (12–27 V) and electrode distance (3–5 cm) on mean size of Cu nanoparticles. The mean particle size of 21.55 nm was obtained with the electrodeposition parameters of (4 g l−1) CuSO4, (3 cm) electrode distance and (27 V) electrode potential difference. The particle size obtained from the experimental result was 20 nm which was very closer to the predicted result (21.5 nm). The size and morphology of Cu nanoparticle were analyzed by using scanning electron microscope and X-ray diffraction technique.

Details

ISSN :
22147853
Volume :
45
Database :
OpenAIRE
Journal :
Materials Today: Proceedings
Accession number :
edsair.doi...........743c6548b4fc223866256e4e6bdafb70
Full Text :
https://doi.org/10.1016/j.matpr.2020.02.801