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ChemInform Abstract: Rapid, One-Pot Conversion of Aryl Fluorides into Phenols with 2-Butyn-1-ol and Potassium t-Butoxide in DMSO

Authors :
Jeremy I. Levin
Mila T. Du
Source :
ChemInform. 33
Publication Year :
2010
Publisher :
Wiley, 2010.

Abstract

Aryl fluorides react rapidly with 2-butyn-1-ol and potassium t-butoxide in DMSO under microwave irradiation to give propargylic ethers. These ethers isomerize in situ to the corresponding allenyl ethers, which hydrolyze on work-up to give phenols in good yield.

Details

ISSN :
15222667 and 09317597
Volume :
33
Database :
OpenAIRE
Journal :
ChemInform
Accession number :
edsair.doi...........73a37d3404458d9ed79941b51d54d69b