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Nematic-isotropic interfaces in semiflexible polymer blends

Authors :
Boris Y. Drovetsky
Chi H. Mak
Andrea J. Liu
Source :
The Journal of Chemical Physics. 111:4334-4342
Publication Year :
1999
Publisher :
AIP Publishing, 1999.

Abstract

We present calculations of the anisotropy of the tension of interfaces separating an isotropic phase rich in a flexible polymer from a nematic phase rich in a semiflexible polymer. We find that the interfacial tension is always lower when the director is parallel to the plane of the interface than when it is perpendicular. The ratio of the tension in the perpendicular to parallel case can be quite large, of order 5 or so, depending on the strength of the nematic interactions. We also find that the interfacial width is always lower in the parallel case even though the tension is lower; this is because the orientational density prefers parallel alignment of chains at the interface.

Details

ISSN :
10897690 and 00219606
Volume :
111
Database :
OpenAIRE
Journal :
The Journal of Chemical Physics
Accession number :
edsair.doi...........7384ef5341da43b5ccc183a3527863db
Full Text :
https://doi.org/10.1063/1.479732