A CONVENIENT SYNTHETIC METHOD FOR SCHIFF BASES. THE TRIMETHYLSILYL TRIFLUOROMETHANESULFONATE-CATALYZED REACTION OFN,N-BIS(TRIMETHYLSILYL)AMINES WITH ALDEHYDES AND KETONES

Authors :: Minoru Sekiya
Toshiaki Morimoto
Source :: Chemistry Letters. 14:1371-1372
Publication Year :: 1985
Publisher :: The Chemical Society of Japan, 1985.
Abstract: N,N-Bis (trimethylsilyl)amines react with aldehydes or ketones in the presence of trimethylsilyl trifluoromethanesulfonate to give Schiff bases in high yields. In situ utilization of the reaction solution as the Schiff base is also demonstrated.

Subjects :: chemistry.chemical_classification
Benzaldehyde
chemistry.chemical_compound
Aldimine
Schiff base
Ketone
chemistry
Trimethylsilyl
Trimethylsilyl trifluoromethanesulfonate
Acetal
Organic chemistry
General Chemistry
Aldehyde

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