Reductive coupling of organometals induced by oxidation. Detection of metastable paramagnetic intermediates

Authors :: T. T. Tsou
Jay K. Kochi
Source :: Journal of the American Chemical Society. 100:1634-1635
Publication Year :: 1978
Publisher :: American Chemical Society (ACS), 1978.
Abstract: Die Alkyl-Gruppen in den sechsfachkoordinierten Dialkyl-Fe-Komplexen (I) unterliegen einer intramolekularen, reduktiven Kupplung zu den Alkanen (II), induziert durch die Zersetzung der Komplexe (I) mit Einaquivalent-Oxidantien wie Na-hexachloroiridat(IV), Brz, C12, I2, ICI, Tl(III)-, Ce(IV)-tri- fluoracetat oder Co(III)-acetat.

Subjects :: Coupling (electronics)
Paramagnetism
Crystallography
Colloid and Surface Chemistry
Chemistry
Metastability
General Chemistry
Biochemistry
Catalysis

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