π-Acid Ligands in Iron(III) Porphyrinates. Characterization of Low-Spin Bis(tert-butylisocyanide)(porphyrinato)iron(III) Complexes Having (dxz,dyz)4(dxy)1 Ground States

Authors :: Ilona Turowska-Tyrk,‡,⊥
Peter G. Debrunner,£ and
K. Mohanrao
F. Ann Walker
C. Todd Watson
Habib Nasri
Nikolai V. Shokhirev
W. Robert Scheidt
Source :: Journal of the American Chemical Society. 118:12109-12118
Publication Year :: 1996
Publisher :: American Chemical Society (ACS), 1996.
Abstract: The synthesis and characterization of isocyanide complexes of (porphyrinato)iron(III) species, [(Porph)Fe(t-BuNC)2]ClO4, Porph = OEP, TPP, are reported. The crystal structures of [(TPP)Fe(t-BuNC)2]...

Subjects :: chemistry.chemical_compound
Crystallography
Colloid and Surface Chemistry
chemistry
Isocyanide
General Chemistry
Crystal structure
Photochemistry
Spin (physics)
Biochemistry
Catalysis
Characterization (materials science)

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