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Supramolecular networks through second-sphere coordination based on 1D metal-4,4′-dipyridyldisulfide coordination polymers and hydrogenfumarate or sulfonate anions
- Source :
- Polyhedron. 31:118-127
- Publication Year :
- 2012
- Publisher :
- Elsevier BV, 2012.
-
Abstract
- Four hydrogen-bonded assemblies of formula [M(dpds)2(OH2)2]A2·nH2O (A = anion) are described. These assemblies result from the second-sphere coordination interactions between the 1D coordination polymers [M(dpds)2(OH2)2]2+, M = Zn(II) and Cu(II), dpds = 4,4′-dipyridyldisulfide, and the pyridine-3-sulfonate (3pySO3−) or hydrogenfumarate (Hfum−) anions. Significantly, supramolecular structural variations are observed depending on the presence of water lattice molecules, which formed discrete aggregates when the Hfum− anion was used. The effects of geometrical variations in the building blocks are also evident on using Jahn–Teller-distorted divalent Cu(II) ions or regular octahedral species based on Zn(II) ions. The second-sphere effects on the stabilization of the compounds are illustrated by TGA experiments.
- Subjects :
- chemistry.chemical_classification
Inorganic chemistry
Supramolecular chemistry
Polymer
Ion
Divalent
Inorganic Chemistry
Metal
Crystallography
chemistry.chemical_compound
Sulfonate
chemistry
Octahedron
visual_art
Materials Chemistry
visual_art.visual_art_medium
Molecule
Physical and Theoretical Chemistry
Subjects
Details
- ISSN :
- 02775387
- Volume :
- 31
- Database :
- OpenAIRE
- Journal :
- Polyhedron
- Accession number :
- edsair.doi...........728172448a7e53b09a8b6df834484fdc