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Experimental Stabilization of Unstable Steady States in Oscillatory and Excitable Reaction Systems

Authors :
J. Ross
A. Hjelmfelt
Source :
The Journal of Physical Chemistry. 98:1176-1179
Publication Year :
1994
Publisher :
American Chemical Society (ACS), 1994.

Abstract

A feedback method is used to stabilize unstable stationary states in experiments with the chlorite-iodide reaction. The unstable stationary states occur in oscillatory and excitable regions of constraint space. Stabilization of unstable steady states provides information about these states and may be of practical importance. An analytical study of a model mechanism of this reaction is consistent with the experiments. This feedback method does not create new stationary states but stabilizes unstable stationary states present in the autonomous system. Unlike «thermostat» type methods, knowledge of the exact location of the unstable stationary states of the autonomous system is not required to implement this feedback method

Details

ISSN :
15415740 and 00223654
Volume :
98
Database :
OpenAIRE
Journal :
The Journal of Physical Chemistry
Accession number :
edsair.doi...........724b5e2847b556ed2c9376c71efc7fa1
Full Text :
https://doi.org/10.1021/j100055a022