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ChemInform Abstract: A DAST-Free Route to Aryl(difluoromethyl)phosphonic Esters

Authors :
Howard J. Easterfield
G. S. Cockerill
Jonathan M. Percy
T. P. Lequeux
Kevin Blades
Source :
ChemInform. 27
Publication Year :
2010
Publisher :
Wiley, 2010.

Abstract

The cerium(III)-mediated addition of diethyl (lithiodifluoromethyl)phosphonate to a benzoquinone monoketal allows the synthesis of phenol bearing the (diethoxyphosphonyl)difluoromethyl group via short, scaleable reaction sequences which avoid the use of the DAST reagent.

Subjects

Subjects :
chemistry.chemical_compound
Cerium
chemistry
Aryl
Reagent
chemistry.chemical_element
Phenol
General Medicine
Medicinal chemistry
Phosphonate
Benzoquinone

Details

ISSN :
09317597
Volume :
27
Database :
OpenAIRE
Journal :
ChemInform
Accession number :
edsair.doi...........713c0a7133895975f1ebfb3bbc18b40e
Full Text :
https://doi.org/10.1002/chin.199645199
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