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Stable thiolate adducts of Rh2(OAc)4 – assembly of hexametallic Ni4Rh2 complexes
- Source :
- Dalton Transactions. 51:59-62
- Publication Year :
- 2022
- Publisher :
- Royal Society of Chemistry (RSC), 2022.
-
Abstract
- Thiolate adducts of dirhodium(II) tetraacetate have proven difficult to prepare. We isolated a stable, paramagnetic Ni4Rh2 adduct containing Ni-based metallothiolates bound in axial positions of the Rh24+ core. The adduct formation is accompanied by a change of the magnetic exchange interaction in the dinuclear Ni2 subunits.
- Subjects :
- Inorganic Chemistry
Paramagnetism
Crystallography
Chemistry
Adduct
Magnetic exchange
Subjects
Details
- ISSN :
- 14779234 and 14779226
- Volume :
- 51
- Database :
- OpenAIRE
- Journal :
- Dalton Transactions
- Accession number :
- edsair.doi...........712a2a269fabda8e513d41fec89bad3a
- Full Text :
- https://doi.org/10.1039/d1dt03509f