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Boron nitride nanotubes (BNNTs) decorated Pd-ternary alloy (Pd63·2Ni34·3Co2.5) for H2 sensing
- Source :
- International Journal of Hydrogen Energy. 46:12263-12270
- Publication Year :
- 2021
- Publisher :
- Elsevier BV, 2021.
-
Abstract
- The micro-electro-mechanical system (MEMS)-based field effect transistor (FET) sensor for hydrogen detection was fabricated by modifying the gate electrode with boron nitride nanotubes (BNNTs) decorated Pd-ternary alloy (Pd63·2Ni34·3Co2.5) as a hydrogen sensing layer Electro-thermal properties of the micro-heater embedded under sensor membrane were analyzed by a finite element method (FEM) simulation. The structural and morphological properties of the gate electrode were studied by Raman spectroscopy, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and field emission scanning electron microscopy (FESEM). A variation in gate potential is observed due to the H2 atmosphere that leads to the variation in the depletion region, therefore, changing the current in the channel (BNNTs decorated Pd-ternary alloy). The BNNTs-decorated Pd ternary alloy displayed high sensing response, fast response and recovery time for H2 gas, low power consumption, long-term stability, and wide detection range from 1 to 5000 ppm H2. The drain current of the H2 FET sensor varied significantly at hydrogen gas exposure and increased with H2 concentration. As proposed H2 FET sensor can be utilized to the H2 leak detection system for safe applications.
- Subjects :
- Materials science
Hydrogen
Alloy
Energy Engineering and Power Technology
chemistry.chemical_element
02 engineering and technology
engineering.material
010402 general chemistry
01 natural sciences
symbols.namesake
chemistry.chemical_compound
Depletion region
X-ray photoelectron spectroscopy
Renewable Energy, Sustainability and the Environment
business.industry
021001 nanoscience & nanotechnology
Condensed Matter Physics
0104 chemical sciences
Fuel Technology
chemistry
Boron nitride
Electrode
engineering
symbols
Optoelectronics
Field-effect transistor
0210 nano-technology
business
Raman spectroscopy
Subjects
Details
- ISSN :
- 03603199
- Volume :
- 46
- Database :
- OpenAIRE
- Journal :
- International Journal of Hydrogen Energy
- Accession number :
- edsair.doi...........6f07e5f99207de60c00a9b72b6db0014
- Full Text :
- https://doi.org/10.1016/j.ijhydene.2020.03.216