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Synthesis and characterization of polypropylene glycol-graft-styrene

Authors :
S.N. Kalugin
G.S. Irmukhametova
A.M. Konysbay
El-Sayed Negim
Source :
Kompleksnoe Ispolʹzovanie Mineralʹnogo syrʹâ/Complex Use of Mineral Resources/Mineraldik Shikisattardy Keshendi Paidalanu. 318:5-11
Publication Year :
2021
Publisher :
Institute of Metallurgy and Ore Benefication (Publications), 2021.

Abstract

Grafting polymerization based on polypropylene glycol (PPG) and styrene (St) was synthesized with different composition of styrene using the free radical technique in the presence of potassium persulphate as an initiator. The grafted copolymers (PPG-g-St) used different styrene composition (65/15, 65/25, 65/35), respectively. The grafted copolymers were investigated through FTIR (Fourier-transform spectroscopy), Differential scanning calorimeter and thermogravimetric analyzer. FTIR showed new peaks at 1450 cm-1 and 1135 cm-1 due to the grafting process of St on PPG. Thermal stability of grafted copolymer increases by increasing the ratio of styrene, while Tg decreases by increasing the ratio of styrene.

Details

ISSN :
26166445 and 22245243
Volume :
318
Database :
OpenAIRE
Journal :
Kompleksnoe Ispolʹzovanie Mineralʹnogo syrʹâ/Complex Use of Mineral Resources/Mineraldik Shikisattardy Keshendi Paidalanu
Accession number :
edsair.doi...........6e7b8ba1153a6f3336e070c6958b0fd0
Full Text :
https://doi.org/10.31643/2021/6445.23