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Substitution on Metallaboranes at Boron. Syntheses of closo-1-X-[2,3,4-(η5-C5Me5)3(μ-H)2Co3B2H], X = Cl and OH, and closo-1,5-Cl2-[2,3,4-(η5-C5Me5)3(μ-H)2Co3B2] from closo-[2,3,4-(η5-C5Me5)3(μ-H)2Co3B2H2]
- Source :
- Inorganic Chemistry. 36:554-558
- Publication Year :
- 1997
- Publisher :
- American Chemical Society (ACS), 1997.
-
Abstract
- The reaction of closo-[2,3,4-(η5-C5Me5)3(μ-H)2Co3B2H2], 1, with metal chlorides results in the formation of either closo-1-Cl-[2,3,4-(η5-C5Me5)3(μ-H)2Co3B2H], 2, or closo-1,5-Cl2-[2,3,4-(η5-C5Me5)3...
Details
- ISSN :
- 1520510X and 00201669
- Volume :
- 36
- Database :
- OpenAIRE
- Journal :
- Inorganic Chemistry
- Accession number :
- edsair.doi...........6e4f447ca4b39d176abefa768dc1191f