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Substitution on Metallaboranes at Boron. Syntheses of closo-1-X-[2,3,4-(η5-C5Me5)3(μ-H)2Co3B2H], X = Cl and OH, and closo-1,5-Cl2-[2,3,4-(η5-C5Me5)3(μ-H)2Co3B2] from closo-[2,3,4-(η5-C5Me5)3(μ-H)2Co3B2H2]

Authors :
Thomas P. Fehlner
Kathryn J. Deck
Paula Brenton
Source :
Inorganic Chemistry. 36:554-558
Publication Year :
1997
Publisher :
American Chemical Society (ACS), 1997.

Abstract

The reaction of closo-[2,3,4-(η5-C5Me5)3(μ-H)2Co3B2H2], 1, with metal chlorides results in the formation of either closo-1-Cl-[2,3,4-(η5-C5Me5)3(μ-H)2Co3B2H], 2, or closo-1,5-Cl2-[2,3,4-(η5-C5Me5)3...

Details

ISSN :
1520510X and 00201669
Volume :
36
Database :
OpenAIRE
Journal :
Inorganic Chemistry
Accession number :
edsair.doi...........6e4f447ca4b39d176abefa768dc1191f