Novel surface modifying macromolecules (SMMs) blended polysulfone gas separation membranes by phase inversion technique

In this article an attempt was made to fabricate defect-free asymmetric polysulfone (PSf) membranes for the separation of oxygen and nitrogen. The approach is based on the enhanced delayed demixing by blending surface modifying macromolecules (SMMs) in the casting solution and by immersing the cast film in isopropanol for a certain period before it is immersed in water. Different SMMs, including hydrophobic and charged SMMs, were synthesized, characterized, and blended to the host PSf. It was found that the charged SMM could indeed contribute to the removal of defective pores from the skin layer and enhancement of oxygen/nitrogen selectivity. The experimental results were further interpreted based on the shift of the phase boundary line on the polymer/solvent/nonsolvent triangular diagram, which occurred when SMMs were blended to PSf, due to the change in the polymer/nonsolvent interaction. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012