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Mechanically robust and shape-memory hybrid aerogels for super-insulating applications
- Source :
- Journal of Materials Chemistry A. 5:15048-15055
- Publication Year :
- 2017
- Publisher :
- Royal Society of Chemistry (RSC), 2017.
-
Abstract
- Super-insulating aerogels are promising materials to improve the energy efficiency of buildings. However, fabricating super-insulating yet mechanically robust and shape-memory aerogels remains challenging. Here, we integrate graphene oxide and a block copolymer to fabricate hybrid aerogels with triple networks and systematically study their mechanical and thermal properties. We show that the first network serves as sacrificial bonds and dissipates energy upon deformation, enabling the aerogels to have a high mechanical performance. The second network allows the aerogels to memorize the original permanent shape, and the third network is able to store strain energy and fix the aerogels in a temporary shape by vitrification. Remarkably, the strong phonon-scattering effect generated by the enormous interfaces between the three networks yields an ultra-low solid thermal conductivity of ∼8 mW m−1 K−1. The multi-functionality makes this class of hybrid aerogels particularly suitable for super-insulation applications on complex surfaces and in small spaces of buildings, industry and spacecrafts.
- Subjects :
- Materials science
Renewable Energy, Sustainability and the Environment
Graphene
Oxide
Nanotechnology
02 engineering and technology
General Chemistry
Shape-memory alloy
010402 general chemistry
021001 nanoscience & nanotechnology
01 natural sciences
0104 chemical sciences
law.invention
Strain energy
Condensed Matter::Soft Condensed Matter
chemistry.chemical_compound
Thermal conductivity
chemistry
law
Thermal
General Materials Science
Deformation (engineering)
0210 nano-technology
Efficient energy use
Subjects
Details
- ISSN :
- 20507496 and 20507488
- Volume :
- 5
- Database :
- OpenAIRE
- Journal :
- Journal of Materials Chemistry A
- Accession number :
- edsair.doi...........6c71cb98d5c24ff9edf6e0085d7f7637
- Full Text :
- https://doi.org/10.1039/c7ta02686b