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ChemInform Abstract: Highly Regio- and Diastereoselective Oxazol-5-one Addition to Nitrostyrenes

Authors :
Mercè Font-Bardia
Andrea‐Nekane Balaguer
Teresa Calvet
Ramon Rios
Albert Moyano
Xavier Companyó
Source :
ChemInform. 40
Publication Year :
2009
Publisher :
Wiley, 2009.

Abstract

A convenient and novel oxazol-5-one addition to nitrostyrenes is reported. The reaction is catalyzed by tertiary amines and yields the corresponding adducts with total regio- and diastereoselectivity. The addition exclusively takes place at the C-2 position of oxazol-5-ones, furnishing diastereopure N,O-aminals.

Details

ISSN :
15222667 and 09317597
Volume :
40
Database :
OpenAIRE
Journal :
ChemInform
Accession number :
edsair.doi...........6c2d006978f6de4bb38f0e156055065d
Full Text :
https://doi.org/10.1002/chin.200920116