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Electrocatalytic and energy storage performance of bio-derived sulphur-nitrogen-doped carbon
- Source :
- Journal of Electroanalytical Chemistry. 833:357-369
- Publication Year :
- 2019
- Publisher :
- Elsevier BV, 2019.
-
Abstract
- Sulphur and nitrogen-rich carbon layers (S/N-CLs) have been derived successfully via a simple calcination for high energy applications including supercapacitor and electrocatalytic hydrogen evolution reaction (HER). The flexible working electrode was fabricated using thoroughly analyzed S/N-CLs composite as an active electrode energy material for supercapacitor and HER. The S/N-CLs composite shows a higher specific capacitance of 266 F g−1 at a current density of 0.5 A g−1 and a satisfied cycling stability with 84% capacitance retention even after 5000 cycles of galvanostatic charge-discharge. On the other hand, the synthesized S/N-CLs composite was used as an electrocatalyst for HER and it exhibits an excellent HER performance with an onset overpotential of −75 mV, and a Tafel slope of 73 mV dec−1 in 0.5 M H2SO4 aqueous electrolyte. Also, the S/N-CLs composite displayed good stability and strong durability. The high electrocatalytic activity and stability of S/N-CLs composite toward HER due to the active site of a compound which may originate from the heteroatom-functional groups including N and S in the carbon structure. Overall, the high-performance supercapacitors and enhancing HER based on heteroatom-doped carbon structures could be promising in replacing traditional supercapacitors for many electronic devices and electrocatalyst for HER.
- Subjects :
- Supercapacitor
Tafel equation
Working electrode
Chemistry
General Chemical Engineering
Composite number
chemistry.chemical_element
02 engineering and technology
Overpotential
010402 general chemistry
021001 nanoscience & nanotechnology
Electrocatalyst
01 natural sciences
Capacitance
0104 chemical sciences
Analytical Chemistry
Chemical engineering
Electrochemistry
0210 nano-technology
Carbon
Subjects
Details
- ISSN :
- 15726657
- Volume :
- 833
- Database :
- OpenAIRE
- Journal :
- Journal of Electroanalytical Chemistry
- Accession number :
- edsair.doi...........6badd0200b1f3716976c90c902cfd81e