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ChemInform Abstract: Stereocontrolled Synthesis of Bicyclic Sulfamides via Pd-Catalyzed Alkene Carboamination Reactions. Control of 1,3-Asymmetric Induction by Manipulating Mechanistic Pathways

Authors :
Nicholas R. Babij
Grace M. McKenna
Ryan M. Fornwald
John P. Wolfe
Source :
ChemInform. 45
Publication Year :
2014
Publisher :
Wiley, 2014.

Abstract

Optimized conditions concerning the substrates, the catalyst and the reaction medium favor the desired anti-aminopalladation mechanism to produce the ring systems with a reversed relative stereochemistry at C-3/C-4.

Details

ISSN :
09317597
Volume :
45
Database :
OpenAIRE
Journal :
ChemInform
Accession number :
edsair.doi...........6b664547e52bf79a1e50aef969530be4
Full Text :
https://doi.org/10.1002/chin.201449180