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C5R5–iron complexes (R = H or Me) of polyaromatic hydrocarbons: stabilization of the monoreduced state and large variation of spin distribution as a function of the ligand structures
- Source :
- J. Chem. Soc., Chem. Commun.. :667-669
- Publication Year :
- 1987
- Publisher :
- Royal Society of Chemistry (RSC), 1987.
-
Abstract
- Several new polyaromatic iron complexes have been synthesized with C5H5 or C5Me5 ligands and the synthesis of others is much improved using molten components; cyclic voltammetry shows a considerable stabilization of the FeI state by permethylation of the C5H5 ligand, and a wide range of spin distribution on the polyaromatic ligand: biphenyl ∼ triphenylene ⩽ naphthalene < phenanthrene < pyrene < perylene ⩽ corronene, is found for the C5H5 complexes only.
Details
- ISSN :
- 00224936
- Database :
- OpenAIRE
- Journal :
- J. Chem. Soc., Chem. Commun.
- Accession number :
- edsair.doi...........6b5effc8aefefd8f77b8f7974ca043f7