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Synthesis and Characterization of the Dicobalt Bisporphyrin Complex Linked by 1,2-Phenylene Bridge
- Source :
- Chemistry Letters. 30:538-539
- Publication Year :
- 2001
- Publisher :
- The Chemical Society of Japan, 2001.
-
Abstract
- The structure of a 1,2-phenylene linked dicobalt tetraarylporphyrin dimer was determined by X-ray crystallography and its dioxygen adduct was characterized by absorption and ESR spectroscopies. Since the porphyrin dimer has a long metal–metal distance and a rigid framework against inward bending, the cobalt centers were not bridged by the coordinated dioxygen.
Details
- ISSN :
- 13480715 and 03667022
- Volume :
- 30
- Database :
- OpenAIRE
- Journal :
- Chemistry Letters
- Accession number :
- edsair.doi...........6b57ba40b8140304fc8358f56a2fe9ed