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Synthesis, structural and magnetic investigation of copper(II) coordination polymer based on 5-amino-tetrazolate and isonicotinate mixed ligands
- Source :
- Inorganica Chimica Acta. 410:131-135
- Publication Year :
- 2014
- Publisher :
- Elsevier BV, 2014.
-
Abstract
- A new three-dimensional(3D) coordination polymer, [Cu(atz)(isonic)]n (1) was synthesized hydrothermally from mixed-ligands of Hatz (Hatz = 5-amino-1H-tetrazole) and Hisonic (Hisonic = isonicotinic acid) and corresponding CuII salt. It was characterized by IR spectra, elemental and thermal analysis, structurally and magnetically characterized. In this compound, CuII ions are linked by μ3-atz bridges to give [{Cu2(μ3-atz)2}]2+ cationic layer. The cationic layers are further pillared by isonic ligand and resulted in 3D frameworks with unprecedented topological network. The variable temperature magnetic investigations indicate that compound 1 exhibits typical antiferromagnetic behaviors.
- Subjects :
- chemistry.chemical_classification
Ligand
Coordination polymer
Inorganic chemistry
Cationic polymerization
Salt (chemistry)
Infrared spectroscopy
chemistry.chemical_element
Copper
Inorganic Chemistry
chemistry.chemical_compound
Crystallography
chemistry
Materials Chemistry
Antiferromagnetism
Physical and Theoretical Chemistry
Thermal analysis
Subjects
Details
- ISSN :
- 00201693
- Volume :
- 410
- Database :
- OpenAIRE
- Journal :
- Inorganica Chimica Acta
- Accession number :
- edsair.doi...........6b40d9951b246316ed9cae6e1bec1416