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Regio-defined syntheses of tetra-brominated dibenzo[g,p]chrysene scaffolds with high solubility

Authors :
Shugo Tokai
Kazuki Sakao
Yoshino Fujii
Yuta Taguchi
Tetsuo Iwasawa
Ryuhei Akasaka
Tomoyuki Maruyama
Yasuhiro Matsumoto
Naoki Yoshida
Shinsuke Kamiguchi
Source :
Tetrahedron Letters. 65:152758
Publication Year :
2021
Publisher :
Elsevier BV, 2021.

Abstract

Regio-defined syntheses of tetra-brominated dibenzo[g,p]chrysene (DBC) derivatives are described, with a description of different patterns of the four-bromine-positions. These derivatives were designed with two features: one is installation of butyl groups for being processable in solution-phase, and the other is attachment of bromine atoms for being variable. Thus, these brominated devices would enable us to achieve diversity-oriented preparation of solution-processable DBC derivatives.

Details

ISSN :
00404039
Volume :
65
Database :
OpenAIRE
Journal :
Tetrahedron Letters
Accession number :
edsair.doi...........6930cc3b018ae3a1a7f289f129766d89
Full Text :
https://doi.org/10.1016/j.tetlet.2020.152758