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Intramolecular hydrogen bonds and conformations of mercaptoethanol molecules
- Source :
- Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 38:638-641
- Publication Year :
- 1989
- Publisher :
- Springer Science and Business Media LLC, 1989.
-
Abstract
- 1. The IR spectra of a solution of mercaptoethanol in CCl4 and in gas-phase mercaptoethanol have νXH bands for free OH and SH groups and OH...S and SH...O groups in intramolecular hydrogen bonds. This indicates a conformational multiplicity of the ME molecules. 2. A molecular mechanics calculation indicates the possibility of conformational multiplicity for mercaptoethanol. The energy of the intramolecular OH...S hydrogen bond was evaluated.
Details
- ISSN :
- 15739171 and 05685230
- Volume :
- 38
- Database :
- OpenAIRE
- Journal :
- Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
- Accession number :
- edsair.doi...........693001b1f04ef305abc56acd5afdc9db