ChemInform Abstract: Copper-Catalyzed Silylation of p-Quinone Methides: New Entry to Dibenzylic Silanes

Authors :: Carlos Jarava-Barrera
Mariola Tortosa
Aurora López
Alejandro Parra
Source :: ChemInform. 47
Publication Year :: 2016
Publisher :: Wiley, 2016.
Abstract: An efficient and general copper(I)-catalyzed silylation of p-quinone-methides is described. Non-symmetric dibenzylic silanes are obtained in high yields under mild reaction conditions. These compounds can be used as bench-stable benzylic carbanion precursors.

Subjects :: Reaction conditions
chemistry.chemical_compound
Silanes
Silylation
Chemistry
Polymer chemistry
Copper catalyzed
chemistry.chemical_element
General Medicine
Copper
Quinone
Carbanion

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