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A novel tetrazole functionalized polymer-supported palladium nano-catalyst for the synthesis of various N-benzylated arylcyanamides

Authors :
Alireza Faraji
Somayyeh Heydari
Davood Habibi
Source :
Journal of Alloys and Compounds. 763:891-898
Publication Year :
2018
Publisher :
Elsevier BV, 2018.

Abstract

4-(Benzyloxy)benzyl chloride polymer-bound (BBC-Polym) was functionalized with 1-phenyl-1H-tetrazole-5-thiol (PTT), and the corresponding novel nano-particle Pd catalyst prepared by the subsequent addition of PdCl2 (BBC-Polym@PTT@Pd). The Pd catalyst was characterized using powder XRD, SEM, EDX, ICP, TGA-DTA, and FT-IR spectroscopy. Then, the Pd catalyst was used as an efficient heterogeneous catalyst for the synthesis of various N-benzylated arylcyanamides at 60 °C in acetonitrile.

Details

ISSN :
09258388
Volume :
763
Database :
OpenAIRE
Journal :
Journal of Alloys and Compounds
Accession number :
edsair.doi...........6828c5d670054f5fffa9bc9e35689080