Base-catalyzed fragmentation of 2,3-dioxabicyclo[2.2.1]heptane, the bicyclic peroxide nucleus of prostaglandin endoperoxides: large secondary deuterium kinetic isotope effects

Subjects

Subjects :

Organic peroxide
Heptane
Bicyclic molecule
General Chemistry
Biochemistry
Peroxide
Catalysis
chemistry.chemical_compound
Colloid and Surface Chemistry
chemistry
Fragmentation (mass spectrometry)
Deuterium
Kinetic isotope effect
Organic chemistry
Bond cleavage

Details

ISSN :

15205126 and 00027863

Volume :

106

Database :

OpenAIRE

Journal :

Journal of the American Chemical Society

Accession number :

edsair.doi...........670ffec1048da24208f0f258cf78bf3f

Full Text :

https://doi.org/10.1021/ja00318a034