Enhanced hydrogen evolution reaction on highly stable titania‐supported PdO and Eu2O3nanocomposites in a strong alkaline solution

In this work, PdO/TiO and EuO/TiO nanocomposites (NCs) were synthesized using a new facile, template-free, and one-step solvothermal approach and characterized by several instrumentation techniques. X-ray photoelectron spectroscopy studies revealed the presence of oxidized form of the Pd and Eu nanoparticles within the NC materials (PdO and EuO). The two catalysts exhibited remarkable activity for the hydrogen evaluation reaction (HER) in a strong alkaline solution (4.0 M NaOH) with PdO/TiO catalyst being the best, which recorded an exchange current density (j) of 0.26 mA cm and a Tafel slope (β) of 125 mV dec. Such parameters are not far from those recorded for a commercial Pt/C catalyst (0.71 mA cm and 120 mV dec) performed here under the same operating conditions. EuO/TiO catalyst recorded j and β values of 0.05 mA cm and 135 mV dec. The Tafel slopes 125 and 135 mV dec calculated on the PdO/TiO and EuO/TiO catalysts suggest a HER kinetics controlled by the Volmer step. PdO/TiO catalyzed the HER with a high turnover frequency of 2.3 H/s at 0.2 V versus the reversible hydrogen electrode, while EuO/TiO catalyst only measured a turnover frequency value of 1.25 H/s at the same overpotential. The two catalysts exhibited excellent stability and durability after 10 000 cycles and 72 hours of controlled potential electrolysis at a high cathodic overpotential, reflecting their practical applicability. Scanning electron microscope and X-ray photoelectron spectroscopy examinations revealed that the morphology and chemistry of both catalysts were not altered as a result of the performed long-term stability and durability tests.